In the presence of tensile stress, cracking may occur along grain boundaries and this type of corrosion is frequently called intergranular stress corrosion cracking igscc or simply intergranular corrosion cracking. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. If the phases segregated at the grain boundaries have lower value of electrode. Delanty introduction the majority of instances of stress corrosion cracking scc in highpressure gas pipelines has been associated with the propagation of intergranular cracks. There are several other processes that can lead to intergranular fracture, or preferential crack propagation at the grain boundaries. What is intergranular stress corrosion cracking igscc. Then, the stress corrosion cracking mechanism for various materials in. The intergranular penetrations are attributed to general corrosive attack rather than stress corrosion cracking scc.
The mechanism and modeling of intergranular stress corrosion cracking of nickelchromiumiron alloys exposed to high purity water g young, w wilkening, d morton, e richey, n lewis this report was prepared as an account of work sponsored by the united states government. For this study, res sponsored through pnl 6 twoperson manual inspection teams, and industry. Circumferential corrosion fatigue cracking was mainly driven by thermal stress cycles and corrosion. Stress corrosion cracking scc is the type of failure mechanism caused by a combination of. The relationship between igc and scc susceptibility and the mechanisms of scc in aa6005a extrusions were studied by examining two primary hypotheses. Prior to the discovery of this new form of cracking, scc was thought to be a relatively wellunderstood, intergranular. Intergranular stress corrosion cracking of welded steel twi. Stress corrosion cracking of an austenitic stainless steel. This is, of course, a very complex question for a forum like this. Cracking was mainly transgranular with sections of intergranular branching. Cracking of sensitized stainless steels inspectioneering. Cracks may propagate in a transgranular or intergranular fashion or in a combination of the two. Intergranular corrosion is sometimes also called intercrystalline corrosion or interdendritic corrosion.
Intergranular stress corrosion cracking igscc of alloy 600 in hightemperature, deaerated water or steam has been termed hydrogeninduced igscc. Why is chloride stress corrosion cracking transgranular. Intergranular stress corrosion cracking igscc cracks propagate along the grain boundaries. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline. Stress corrosion is an environmentally induced cracking phenomenon that sometimes occurs when a metal is subjected to a tensile stress and a corrosive environment simultaneously. Stresscorrosion cracking in aluminum alloys is characteristically intergranular. There appears to be no unique mechanism of transgranular stress corrosion cracking, since no single factor is common to all susceptible alloys. Intergranular stress corrosion cracking is common in alloys that are otherwise typically corrosionresistant. This form of corrosion is usually associated with chemical segregation effects impurities have a tendency to be enriched at grain boundaries or specific phases. Stress corrosion cracking scc intergranular scc of an inconel heat exchanger tube with the crack following the grain boundaries. The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steelelectrolyte interface, which are formed by the applied cathodic current to protect the structure 71. Intergranular corrosion and stress corrosion cracking of alloy 600 steam generator tubes that occur in occluded superheated crevices on the secondary side of. Effects of irradiation on intergranular stress corrosion cracking g.
Effects of irradiation on intergranular stress corrosion. Scc propagation was mainly transgranular, but scc propagation of. The postulated mechanisms for stress corrosion cracking of. Intergranular corrosion is localized attack along the grain boundaries, or immediately adjacent to grain boundaries, while the bulk of the grains remain largely unaffected. Intergranular corrosion is caused by microsegregation of impurities and alloying elements on the grains boundaries. The mechanism of intergranular corrosion was summarized by sinyavskii et al. Intergranular stress corrosion cracking igscc is more common than transgranular scc. Study of the oxidation assisted intergranular cracking. Mod01 lec27 pitting corrosion, intergranular corrosion. Recognize the mechanism for igscc and the conditions that make igscc more likely. When assessing nuclear power plant life, stress corrosion cracking scc plays an important role. The mechanism and modeling of intergranular stress. Some recent work have suggested that the mechanism of trans and intergranular stress corrosion cracking are identical.
Intergranular corrosion in practical application, the loss of cross section thickness and the introduction of cracks can have severe consequences for applications like pressure containment. A mechanism for hydrogeninduced intergranular stress. Evidence of intergranular attack iga in the absence of stress, together with dissolution kinetics, indicates that intergranular stress corrosion cracking igscc of ferritic steels in various environments is by a dissolution mechanism. Stress corrosion cracking international institute of. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. Microvoid nucleation and coalescence at inclusions or second. Intergranular stress corrosion cracking igscc is a mode of subcritical crack propagation in susceptible nickelbased alloys and austenitic stainless steels used in power generation. Cracking of stainless steel nozzle sleeve metallurgical. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. Transgranular cracking is a key characteristic of chloride induced stress corrosion cracking in austenitic stainless steels.
On the mechanism of intergranular corrosion of aluminum alloys. We believe these cracks are initiated by the nucleation of a high density of bubbles on the grain. Modelling intergranular stress corrosion cracking in. Atmospheric stress corrosion cracking susceptibility of welded and unwelded 304, 304l, and. Highpurity copper is immune to stress corrosion cracking in most. Extensive laboratory testing has shown that intergranular stress corrosion cracking igscc requires the presence of the following three key elements. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns.
Crack indications were found in 12 instrument nozzles. The mechanism of transgranular stress corrosion cracking tgscc that was proposed by edeleanu and forty and sieradzki and newman recognized an often neglected aspect of tgscc, namely, the brittle, cleavagelike appearance of the fracture surface. Stress corrosion cracking scc is a sudden and difficulttopredict severe degradation mode. The results indicate that the electrochemical contribution to the scc of cu30au in 0. Mechanisms and modeling of stress corrosion cracking in.
Stress corrosion cracking can proceed in one of two ways. It is associated with the simultaneous presence of a number of factors. The number of different types of components that have experienced cracking has. Setup and results of a grain scale model of intergranular cracking. Those pictures show that the weld nugget is sensitive to pitting corrosion when it is not submitted to a mechanical loading gure 3a. Intergranular stress corrosion cracking igscc of austenitic stainless steels, usually aisi 304 steel, is a serious problem in boiling water reactors bwr. Some of the shallow intergranular penetrations were driven to significant depths due to corrosion fatigue. Though it is easy to identify intergranular cracking, pinpointing the cause is more complex as the mechanisms are more varied, compared to transgranular fracture. Modelling of intergranular stress corrosion cracking mechanism kth. Intergranular stress corrosion cracking of copper a case study. Occasionally, both types of cracking are observed in a failure. Transgranular stress corrosion cracking of highpressure pipelines in contact with solutions of near neutral ph r. This is not to be confused with similar phenomena such as hydrogen embrittlement, in which the metal is embrittled by hydrogen, often resulting in the formation of cracks.
Intergranular corrosion and stress corrosion cracking of extruded. Transgranular stress corrosion cracking an overview. On the stress corrosion cracking mechanisms of austenitic. Stress corrosion cracking in light water reactors iaea scientific. Transgranular corrosion is also known as intragranular corrosion and transcrystalline corrosion. Observations of intergranular stress corrosion cracking in. Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Atmospheric stress corrosion cracking susceptibility of. Mechanistic aspects of intergranular stress corrosion. The results obtained do not provide a complete understanding of the mechanism of sensitisation to intergranular stress corrosion cracking in welded smss but are consistent with a mechanism based on formation of crcarbides and associated crdepleted zones. The driving force of intergranular corrosion is the difference between the electrode potentials of the grain boundary and the grain itself, which form a galvanic cell in presence of an electrolyte. Intergranular stress corrosion cracking igscc is the progressive nucleation and growth of cracks by localized corrosion along the grain boundaries in metals in the presence of stress or strain. Kallol mondal,department of metallurgy and material science,iit kanpur.
Characterization of intergranular stress corrosion. It can lead to unexpected sudden failure of normally ductile metal. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. At low values of stress, failure occurred by brittle intergranular cracking, and at high values of stress, failure occurred by brittle transgranular cracking. A research program focused on understanding the intergranular corrosion igc and stress corrosion cracking scc behavior of aa6005a aluminum extrusions is presented in this dissertation. In general, however, all susceptible alloys are unstable in the environment concerned but are largely protected by a surface film that is locally destroyed in some way. Transgranular stress corrosion cracking tgscc cracks run through the individual grains. In the presence of tensile strength, cracking may occur along grain boundaries and this type of corrosion is frequently called interranular stress corrosion cracking igscc or simply intergranular corrosion cracking. The stress corrosion cracking scc of aluminum alloys is a welldocumented phenomenon, but there is considerable disagreement in the scientific literature as to what mechanism causes it.
Intergranular stress corrosion cracking tends to occur when preexisting inter granular fractures are present. A joint industry project is described, that tested the current understanding of the mechanism of sensitisation to intergranular stress corrosion cracking of welded. Stress corrosion cracking increases with the temperature of the corroding medium. Specifically, this type of corrosion occurs as a result of the boundaries of grains being more susceptible to.
This is because of the intermolecular space that exists due to the interaction of two or more components. Intergranular stress corrosion cracking an overview. Evaluation of risk associated with intergranular stress corrosion. Both intergranular and transgranular stress corrosion cracking are. Intergranular stress corrosion cracking igscc has been detected in a number of boiling water reactor bwr vessel internals. Erosion corrosion generally, this movement is quite rapid and mechanical wear effects or abrasions are involved. The interaction of corrosion fatigue and stresscorrosion. In this study, by using the load pulsing technique, it has been determined that the velocity in intergranular scc is about 2 to 3 times higher than tmnsgranular scc.
Room temperature stress corrosion cracking of titanium. Ultrasonic inspection reliability for intergranular stress corrosion. Intergranular cracks follow the grain boundaries in the metal. Anstenitic stainless steel, stress corrosion cracking mechanism. Transgranular stress corrosion cracking of highpressure.